Autoclaved Oxidative Leaching of Sulfide Concentrate Containing - Gold Arsenic (II)

The results of these tests, presented two arsenic pyrite oxidation most likely related to the mechanism :( 1) directly under the oxidation action of oxygen, (2) oxidation under action of the ion Fe (â…¢). At this time, the action of oxygen enables Fe ( II) to form Fe ( III ).

In the absence of oxygen, the concentrations of CFe (III) and H 2 SO 4 in the acidic solution of ferric sulfate are respectively 10 grams / L and 26.4 grams / liter) The original material leaching test (Fig. 2 , a ) results show that under such conditions, the oxidation rate of arsenopyrite and arsenic pyrite under oxygen pressure, but without artificial addition of Fe (III) ions The oxidation rate is not bad. This proves that oxidation according to the second mechanism is possible in principle. in 120 °C with 130 °C Oxidation process anomalies may occur when - a predetermined number of related form of elemental sulfur, as they are rapidly oxidized at a high temperature.

Related to arsenopyrite in accordance with section - the possibility of oxidation of a mechanism is very complex. Although this - mechanism is possible in principle, it does not cause doubt (at least in the initial stage of oxidation, because the concentration of Fe ( III ) ions in the solution is extremely low), but it is evaluated by direct experiment. this - in the whole mechanism of the oxidation process of the role is quite complex. This is because there is an oxidation product of pyrite and arsenopyrite- Fe (III) ions in the solution itself . Therefore, the following method is utilized, that is, under the action of oxygen (the temperature is 100 °C And H 2 SO 4 concentration is 26.4 grams / L and Fe ( 111 ) concentration is 10 grams / liter), the concentrate is oxidized in an acidic solution of ferric sulphate. It can be concluded that in the case where the oxidation process is carried out according to the second mechanism, the influence of the partial pressure of oxygen on the oxidation rate is very small and can be ignored. This is because in the case of a significant excess of Fe (III) ions, the concentration can be considered to be fixed and equal to the original concentration, rather than the speed of their regeneration process.

These test results (FIG. 2.6) shows that, under the action of oxygen, arsenopyrite oxidation rate in the ferric sulfate solution in playing faster than in the absence of oxygen - more. So these   The test results show that the arsenic pyrite is oxidized according to the above two mechanisms.

In industry, the processing conditions employed arsenic sulphide concentrates, each half and what percentage of these two mechanisms, it will depend on a particular implementation leaching autoclave leaching. However, in all cases it should be expected that when the Fe (III) concentration in the solution is relatively high, the relative specific gravity of the second mechanism will increase as the leaching process proceeds.

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